The rigidity and chelation effect of ligands on the hydrogen evolution reaction catalyzed by Ni(<scp>ii</scp>) complexes-Reference-Cited by-同舟云学术

The rigidity and chelation effect of ligands on the hydrogen evolution reaction catalyzed by Ni(ii) complexes

Published:2024 Issue:4 Volume:53 Page:1680-1690
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mishra Anjali¹,Mishra Gaurav Kumar²,Anamika ¹,Singh Nanhai¹,Kant Rama²^ORCID,Kumar Kamlesh¹^ORCID

Affiliation:

1. Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi 221005, India

2. Department of Chemistry, University of Delhi, Delhi-110007, India

Abstract

Heteroleptic Ni(ii) dithiolate complexes containing phosphine ligands are investigated as electrocatalyst for proton reduction. This study highlights the effect of rigidity and chelation properties of phosphine ligands on electrocatalytic activity.

Funder

University Grants Commission

Council of Scientific and Industrial Research, India

Banaras Hindu University

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03932C

Reference75 articles.

1. Mononuclear nickel(II) dithiolate complexes with chelating diphosphines: Insight into protonation and electrochemical proton reduction

2. Applications of Nickel‐Based Electrocatalysts for Hydrogen Evolution Reaction

3. A square-planar nickel dithiolate complex as an efficient molecular catalyst for the electro- and photoreduction of protons

4. Mononuclear nickel(ii) complexes as electrocatalysts in hydrogen evolution reactions: effects of alkyl side chain lengths

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