PhI(OAc)<sub>2</sub>-mediated aminoacyloxylation of β,γ-unsaturated hydrazones using Togni reagent II as an acyloxyl precursor-Reference-Cited by-同舟云学术

PhI(OAc)₂-mediated aminoacyloxylation of β,γ-unsaturated hydrazones using Togni reagent II as an acyloxyl precursor

Published:2023 Issue:33 Volume:21 Page:6757-6761
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Jiang Dong-Fang¹^ORCID,Qi Zhenjie²^ORCID,Li Dengfeng¹,Wen Si-Miaomiao¹,Liu Zhao¹,Hao Wen-Juan³^ORCID,Jiang Bo³^ORCID

Affiliation:

1. Hunan Provincial Key Laboratory of the Research and Development of Novel Pharmaceutical Preparations, Changsha Medical University, Provincial First-Class Applied Discipline (Pharmacy), Changsha, 410219, China

2. Department of Engineering, Jining University, Qufu, Shandong, 273155, P. R. China

3. School of Chemistry & Chemical Engineering, Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Jiangsu Normal University, Xuzhou 221116, P. R. China

Abstract

A metal-free protocol for the direct construction of C(sp2)–N and C–O bonds via a PhI(OAc)2-mediated dehydrogenative aminoacyloxylation of β,γ-unsaturated hydrazones with Togni reagent II is reported.

Funder

Natural Science Foundation ofHunan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/OB/D3OB01125A

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