Capacity-limiting mechanisms in Li/O2 batteries

Author:

Liu Jing123,Khaleghi Rahimian Saeed4563,Monroe Charles W.78910

Affiliation:

1. The Dow Chemical Company

2. Midland

3. USA

4. University of Michigan

5. Chemical Engineering

6. Ann Arbor

7. University of Oxford

8. Department of Engineering Science

9. Oxford

10. UK

Abstract

A continuum model of an aprotic lithium/oxygen battery is validated against experimental first-discharge data and used to examine how the apparent cell capacity is affected by macroscopic multicomponent mass transfer, interfacial kinetics, and electronic conduction or tunneling through the discharge product.

Funder

Division of Chemical, Bioengineering, Environmental, and Transport Systems

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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