Biologically relevant and energetically significant cooperative ternary (π–π)2/(π–π)1/(π–π)2 assemblies and fascinating discrete (H2O)21 clusters in isostructural 2,5-pyridine dicarboxylato Co(ii) and Zn(ii) phenanthroline compounds: antiproliferative evaluation and theoretical studies

Abstract

Cytotoxicity in cancer cells with structure activity relationship has been explored in isostructural Co(ii) and Zn(ii) compounds involving energetically significant cooperative (π–π)₂/(π–π)₁/(π–π)₂ assemblies and fascinating (H₂O)₂₁ clusters.