Scrutinizing ligand exchange reactions in the formation of the precious group metal–organic framework RuII,II-HKUST-1: the impact of diruthenium tetracarboxylate precursor and modulator choice

Author:

Heinz Werner R.12345,Staude Dominik12345ORCID,Mayer David12345,Bunzen Hana67895ORCID,Fischer Roland A.12345ORCID

Affiliation:

1. Chair of Inorganic and Metal-Organic Chemistry

2. Department of Chemistry and Catalysis Research Center

3. Technical University of Munich

4. 85748 Garching

5. Germany

6. Chair of Solid-State and Materials Chemistry

7. Institute of Physics

8. University of Augsburg

9. 86159 Augsburg

Abstract

The high surface area univalent Ru(ii) analogue of HKUST-1 (Ru3BTC2; BTC = 1,3,5 benzendicarboxylate) is synthesized by the coordination modulated controlled secondary building unit approach.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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