Synthesis, structure, and reactivity of uranium(vi) nitrides-Reference-Cited by-同舟云学术

Synthesis, structure, and reactivity of uranium(vi) nitrides

Published:2021 Issue:23 Volume:12 Page:8096-8104
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Barluzzi Luciano¹²³⁴,Hsueh Fang-Che¹²³⁴,Scopelliti Rosario¹²³⁴^ORCID,Atkinson Benjamin E.⁵⁶⁷⁸,Kaltsoyannis Nikolas⁵⁶⁷⁸^ORCID,Mazzanti Marinella¹²³⁴^ORCID

Affiliation:

1. Insititut des Sciences et Ingénierie Chimiques

2. Ecole Polytechnique Fédérale de Lausanne (EPFL)

3. 1015 Lausanne

4. Switzerland

5. Department of Chemistry

6. University of Manchester

7. Manchester

8. UK

Abstract

The first examples of molecular compounds containing the cyclic (U(vi)N)₂ and (U(v)U(vi)N)₂ cores were obtained by oxidation of the (U(v)U(v)N)₂ analogue. Different bonding within these complexes yields different stability and reactivity with CO and H₂.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

École Polytechnique Fédérale de Lausanne

University of Manchester

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01796A

Reference78 articles.

1. Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand