Mechanochemical reaction kinetics scales linearly with impact energy

Author:

Vugrin Leonarda1,Carta Maria2,Lukin Stipe1,Meštrović Ernest3ORCID,Delogu Francesco2ORCID,Halasz Ivan1ORCID

Affiliation:

1. Ruđer Bošković Institute, Bijenička c. 54, 10000 Zagreb, Croatia

2. Department of Mechanical, Chemical and Materials Engineering, University of Cagliari, CSGI Cagliari research unit, via Marengo 2, 09123 Cagliari, Italy

3. Department of Chemistry, Faculty of Science, University of Zagreb, Horvatovac 102a, 10000 Zagreb, Croatia

Abstract

Inelastic collisions of in ball milling provide energy to drive the chemical transformation which is, for purely mechanically driven reactions, linear with the energy dose received.

Funder

European Cooperation in Science and Technology

Hrvatska Zaklada za Znanost

Università degli Studi di Cagliari

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

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