Heteroleptic lanthanide amide complexes bearing carbon-bridged bis(phenolate) ligands: synthesis, structure and their application in the polymerization of ε-caprolactone

Author:

Zhou Yan-Xu12345,Zhao Jing12345,Peng Ling12345,Wang Yu-Long12345,Tao Xian12345,Shen Ying-Zhong12345

Affiliation:

1. Applied Chemistry Department

2. School of Material Science & Engineering

3. Nanjing University of Aeronautics & Astronautics

4. Nanjing

5. P. R. China

Abstract

A convenient method for the synthesis of anionic lanthanide amide complexes bearing carbon-bridged bis(phenolate) ligands is described and the catalytic activity of the complexes in the ring-opening polymerization of ε-caprolactone was studied.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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