Enhancing structural control in covalent organic frameworks through steric interaction-driven linker design

Author:

Winter Alena1,Hamdi Farzad23ORCID,Eichhöfer Andreas4ORCID,Saalwächter Kay5ORCID,Kastritis Panagiotis L.236,Haase Frederik17ORCID

Affiliation:

1. Institute of Chemistry, Faculty of Natural Sciences II, Martin-Luther-Universität Halle-Wittenberg Halle/Saale, Germany

2. Department of Integrative Structural Biochemistry, Institute of Biochemistry and Biotechnology, Martin Luther University Halle-Wittenberg, Halle/Saale, Germany

3. Interdisciplinary Research Center HALOmem, Charles Tanford Protein Center & Biozentrum, Martin Luther University Halle-Wittenberg, Halle/Saale, Germany

4. Institute for Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Eggenstein-Leopoldshafen, Germany

5. Institute of Physics, Martin-Luther-Universität Halle-Wittenberg, Halle/Saale, Germany

6. Institute of Chemical Biology, National Hellenic Research Foundation, Athens, Greece

7. Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), Eggenstein-Leopoldshafen, Germany

Abstract

Using a linker with bulky functional groups encourages kagome formation, while blocking square-lattice network formation in Covalent Organic Frameworks (COFs).

Funder

Karlsruhe Institute of Technology

Deutsche Forschungsgemeinschaft

Fonds der Chemischen Industrie

Bundesministerium für Bildung und Forschung

Martin-Luther-Universität Halle-Wittenberg

Publisher

Royal Society of Chemistry (RSC)

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