Spin transition and symmetry-breaking in new mononuclear FeII tren-complexes with up to 38 K hysteresis around room temperature

Author:

Seredyuk Maksym12ORCID,Znovjyak Kateryna12,Valverde-Muñoz Francisco Javier1ORCID,Muñoz M. Carmen3ORCID,Fritsky Igor O.2ORCID,Amirkhanov Volodymyr M.2,Real Jose A.1ORCID

Affiliation:

1. Departament de Quimica Inorgànica, Institut de Ciencia Molecular (ICMol), Universitat de València, Valencia, Spain

2. Department of Chemistry, Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Street, 01601, Kyiv, Ukraine

3. Departamento de Fisica Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46022, Valencia, Spain

Abstract

New FeII complexes based on the well-known tripodand ligand type undergo abrupt hysteretic spin transition due to the symmetry-breaking in the room temperature region.

Funder

Agencia Estatal de Investigación

Generalitat Valenciana

European Commission

Ministry of Education and Science of Ukraine

Taras Shevchenko National University of Kyiv

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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