Oxidative functionalization of C–H compounds induced by the extremely efficient osmium catalysts (a review)

Author:

Shul'pin Georgiy B.12345ORCID,Vinogradov Mikhail M.6234ORCID,Shul'pina Lidia S.6234ORCID

Affiliation:

1. Semenov Institute of Chemical Physics

2. Russian Academy of Sciences

3. Moscow

4. Russia

5. Plekhanov Russian University of Economics

6. Nesmeyanov Institute of Organoelement Compounds

Abstract

In recent years, osmium complexes have found applications not only in thecis-hydroxylation of olefins but also very efficient in the oxygenation of C–H compounds (saturated and aromatic hydrocarbons and alcohols) by hydrogen peroxide as well as organic peroxides.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference254 articles.

1. G. B. Shul'pin , Organic Reactions Catalysed by Metal Complexes , Nauka , Moscow , 1988

2. C–H functionalization: thoroughly tuning ligands at a metal ion, a chemist can greatly enhance catalyst's activity and selectivity

3. Homogeneous Functionalization of Methane

4. Discrete Molecular Catalysts for Methane Functionalization

5. N. M. Emanuel , E. T.Denisov and Z. K.Maizus , Chain Reactions of Hydrocarbon Oxidation in the Liquid Phase , Nauka , Moscow , 1965

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