Increasing H2SO4 contents in disulfates cresting in the new hydrogenium-bis-hydrogendisulfate anion [H(HS2O7)2]−: Li2[S2O7]·H2SO4, Li[HS2O7], and Li[H(HS2O7)2]
Author:
Affiliation:
1. Justus-Liebig-University of Gießen
2. Institute of Inorganic and Analytical Chemistry
3. D-35392 Gießen
4. Germany
Abstract
In mixtures of H2SO4 and SO3 or even in neat SO3 a number of acidic disulfates could be prepared displaying unique hydrogen bond systems.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ02388F
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1. Temperature- and solvate-dependent disorder in the crystal structure of [PNP]+[HSO4]−;Zeitschrift für Naturforschung B;2019-03-20
2. Festkörperchemie 2016;Nachrichten aus der Chemie;2017-03
3. Hydrogenium-bis-hydrogensulfate anions adjacent to [S2O7]2− in Rb3[S2O7][H(HSO4)2]: a structural evidence of the increasing acidity of polysulfuric acids with growing chain length;Zeitschrift für Naturforschung B;2016-12-09
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