A 5.3 nm giant metal–organic cage and its supramolecular gel for the formation of dye molecular ionic pairs

Author:

Li Kaixiu1,Huang Jian1,Wang Shi-Cheng2,Li Zhengguang1,Wang Jun3,Li Yiming1,Chen Mingzhao3,Chan Yi-Tsu2ORCID,Liu Die1ORCID,Wang Pingshan13ORCID

Affiliation:

1. Department of Organic and Polymer Chemistry, Hunan Key Laboratory of Micro & Nano Materials Interface Science, College of Chemistry and Chemical Engineering, Central South University, Changsha, Hunan 410083, China

2. Department of Chemistry, National Taiwan University, Taipei 10617, Taiwan

3. Institute of Environmental Research at Greater Bay Area, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou 510006, China

Abstract

A giant terpyridine-based metal–organic cage with multiple ion pairs and intrinsic cavities was synthesized and the corresponding metal–organic gel displayed good adsorption performance via electrostatic and other non-covalent interactions.

Funder

Fundamental Research Funds for Central Universities of the Central South University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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