An expeditious and efficient bromomethylation of thiols: enabling bromomethyl sulfides as useful building blocks
Author:
Affiliation:
1. Departamento de Química
2. Centro de Investigación y de Estudios Avanzados (Cinvestav)
3. 07360 Ciudad de México
4. México
5. Facultad de Ciencias
6. Universidad Nacional Autónoma de México
7. Ciudad Universitaria
8. Ciudad de México
Abstract
A new method for the bromomethylation of thiols using paraformaldehyde and HBr/AcOH, minimizes the generation of toxic byproducts. Synthetic utility of α-bromomethyl sulfides was demonstrated through umpolung and free radical chemistry.
Funder
Consejo Nacional de Ciencia y Tecnología
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA04002H
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