Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo6Cl8}Cl5□]− (□ = lacuna)-Reference-Cited by-同舟云学术

Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo₆Cl₈}Cl₅□]⁻ (□ = lacuna)

Published:2023 Issue:41 Volume:59 Page:6243-6246
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Denis Antoine¹,Tymínska Nina²,Delhaye Thomas¹,Molard Yann²^ORCID,Gerbaux Pascal³^ORCID,De Winter Julien³^ORCID,Himdi Mohamed¹,Castel Xavier¹^ORCID,Costuas Karine²^ORCID,Cordier Stéphane²^ORCID,Rondeau David¹

Affiliation:

1. Univ Rennes, CNRS, Institut d'Electronique et des Technologies du numéRique – UMR 6164, Rennes F-35000, France

2. Univ Rennes, Institut des Sciences Chimiques de Rennes – UMR 6226, Rennes F-35000, France

3. Organic Synthesis and Mass Spectrometry Laboratory, Interdisciplinary Center for Mass Spectrometry (CISMa), University of Mons – UMONS, 23 Place du Parc, Mons 7000, Belgium

Abstract

The Janus-reactivity character of the monoanion [{Mo6Cli8}Cla5□a]− that leads to an unprecedented self-reactivity is proved by CID-MS-MS and quantum chemical studies.

Funder

Grand Équipement National De Calcul Intensif

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC01187A

Reference24 articles.

1. A review on functional nanoarchitectonics nanocomposites based on octahedral metal atom clusters (Nb₆, Mo₆, Ta₆, W₆, Re₆): inorganic 0D and 2D powders and films

2. Recent developments on luminescent octahedral transition metal cluster complexes towards biological applications

3. Molecular Clusters: Nanoscale Building Blocks for Solid-State Materials

4. Super Atomic Clusters: Design Rules and Potential for Building Blocks of Materials

5. Clusters, Superatoms, and Building Blocks of New Materials

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Game of Crowns: Na⁺Is Coming! Red NIR-Emissive Hybrid Liquid Crystals Containing Discotic Crown Ethers and Na₂Mo₆X₈ⁱCl₆(Xⁱ= Cl or Br);ACS Applied Materials & Interfaces;2023-08-11