Electrophilic and nucleophilic gas phase reactivity of the Janus cluster-based anions [{Mo6Cl8}Cl5□] (□ = lacuna)

Author:

Denis Antoine1,Tymínska Nina2,Delhaye Thomas1,Molard Yann2ORCID,Gerbaux Pascal3ORCID,De Winter Julien3ORCID,Himdi Mohamed1,Castel Xavier1ORCID,Costuas Karine2ORCID,Cordier Stéphane2ORCID,Rondeau David1

Affiliation:

1. Univ Rennes, CNRS, Institut d'Electronique et des Technologies du numéRique – UMR 6164, Rennes F-35000, France

2. Univ Rennes, Institut des Sciences Chimiques de Rennes – UMR 6226, Rennes F-35000, France

3. Organic Synthesis and Mass Spectrometry Laboratory, Interdisciplinary Center for Mass Spectrometry (CISMa), University of Mons – UMONS, 23 Place du Parc, Mons 7000, Belgium

Abstract

The Janus-reactivity character of the monoanion [{Mo6Cli8}Cla5□a] that leads to an unprecedented self-reactivity is proved by CID-MS-MS and quantum chemical studies.

Funder

Grand Équipement National De Calcul Intensif

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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