Enantioselective synthesis of chiral multicyclic γ-lactones via dynamic kinetic resolution of racemic γ-keto carboxylic acids-Reference-Cited by-同舟云学术

Enantioselective synthesis of chiral multicyclic γ-lactones via dynamic kinetic resolution of racemic γ-keto carboxylic acids

Published:2020 Issue:1 Volume:7 Page:104-108
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Xiong Zhichao¹²³⁴⁵,Tian Jiangyan¹²³⁴⁵,Xue Peng¹²³⁴⁵,Zhang Xumu⁶⁷⁸⁹^ORCID,Lv Hui¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Biomedical Polymers of Ministry of Education & College of Chemistry and Molecular Sciences

2. Engineering Research Center of Organosilicon Compounds & Materials

3. Ministry of Education

4. Sauvage Center for Molecular Sciences

5. Wuhan University

6. Shenzhen Grubbs Institute and Department of Chemistry

7. South University of Science and Technology of China

8. Shenzhen

9. P. R. China

Abstract

Ru-Catalyzed asymmetric transfer hydrogenation of γ-keto carboxylic acids has been achieved, affording chiral multicyclic γ-lactones in high yields with excellent diastereo- and enantioselectivities.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hubei Province

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QO/C9QO01047E

Reference78 articles.

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