Lattice solvent- and substituent-dependent spin-crossover in isomeric iron(ii) complexes

Author:

Kuppusamy Senthil Kumar1ORCID,Mizuno Asato2,Kämmerer Lea3ORCID,Salamon Soma3ORCID,Heinrich Benoît4ORCID,Bailly Corinne5,Šalitroš Ivan67ORCID,Wende Heiko3ORCID,Ruben Mario128

Affiliation:

1. Institute of Quantum Materials and Technologies (IQMT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

2. Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

3. University of Duisburg-Essen, Faculty of Physics and Center for Nanointegration Duisburg-Essen (CENIDE), Lotharstraße 1, 47057 Duisburg, Germany

4. Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), CNRS-Université de Strasbourg, 23, rue du Loess, BP 43, 67034 Strasbourg Cedex 2, France

5. Service de Radiocristallographie, Fédération de Chimie Le Bel UAR2042 CNRS-Université de Strasbourg, 1 rue Blaise Pascal, BP 296/R8, 67008 Strasbourg cedex, France

6. Central European Institute of Technology, Brno University of Technology, Purkyňova 123, 61200 Brno, Czech Republic

7. Department of Inorganic Chemistry, Faculty of Chemical and Food Technology, Slovak University of Technology in Bratislava, Bratislava SK-81237, Slovakia

8. Centre Européen de Sciences Quantiques (CESQ), Institut de Science et d'Ingénierie, Supramoléculaires (ISIS), 8 allée Gaspard Monge, BP 70028, 67083 Strasbourg Cedex, France

Abstract

Studies on iron(ii) complexes composed of isomeric ligands reveal that one of the complexes—1·CH3CN—undergoes bi-stable spin-state switching with T1/2 = 298 K and ΔT1/2 = 44 K.

Funder

Fédération pour la Recherche sur le Cerveau

Alexander von Humboldt-Stiftung

Japan Society for the Promotion of Science

Deutsche Forschungsgemeinschaft

Agentúra na Podporu Výskumu a Vývoja

Vedecká Grantová Agentúra MŠVVaŠ SR a SAV

Grantová Agentura České Republiky

Publisher

Royal Society of Chemistry (RSC)

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