Globally stabilized bent carbon–carbon triple bond by hydrogen-free inorganic–metallic scaffolding Al4F6

Author:

Xue Ying-ying12345,Zhang Ying12345,Cui Zhong-hua6345ORCID,Ding Yi-hong12345ORCID

Affiliation:

1. Laboratory of Theoretical and Computational Chemistry

2. Institute of Theoretical Chemistry

3. Jilin University

4. Changchun 130023

5. P. R. China

6. Institute of Atomic and Molecular Physics

Abstract

We report a novel C2Al4F6-01 with metal–inorganic Al4F6-scaffolding, which differs from hitherto known bent-CC types, which all involve carbon-based scaffoldings.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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4. S.Patai , The Chemistry of Carbon-Carbon Triple Bonds , Wiley , New York , 1978 , pp. 1–199

5. Hidden Dicarbene Nature of Acetylenes and Captodative Bonding on Carbon

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