Absolute and relative facial selectivities in organocatalytic asymmetric chlorocyclization reactions-Reference-Cited by-同舟云学术

Absolute and relative facial selectivities in organocatalytic asymmetric chlorocyclization reactions

Published:2018 Issue:11 Volume:9 Page:2898-2908
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Salehi Marzijarani Nastaran¹²³⁴,Yousefi Roozbeh¹²³⁴,Jaganathan Arvind⁵⁶⁴,Ashtekar Kumar Dilip¹²³⁴,Jackson James E.¹²³⁴^ORCID,Borhan Babak¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Michigan State University

3. Michigan 48824

4. USA

5. Dow AgroSciences LLC

6. Indianapolis

Abstract

For four related 1,1-disubstituted olefins, (DHQD)₂PHAL-catalyzed asymmetric chlorocyclization delivers Cl⁺ uniformly to one π face, but cyclizes with strong but differing net syn vs. anti addition.

Funder

National Institute of General Medical Sciences

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/SC/C7SC04430E

Reference92 articles.

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3. Recent advances in asymmetric intra- and intermolecular halofunctionalizations of alkenes

4. Catalytic, Asymmetric Halofunctionalization of Alkenes-A Critical Perspective

5. New Catalytic Approaches towards the Enantioselective Halogenation of Alkenes

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