Remarkable effect of alkalis on the chemoselective hydrogenation of functionalized nitroarenes over high-loading Pt/FeOx catalysts

Author:

Wei Haisheng12345,Ren Yujing12345,Wang Aiqin12345ORCID,Liu Xiaoyan12345,Liu Xin12345,Zhang Leilei12345,Miao Shu12345,Li Lin12345,Liu Jingyue6789,Wang Junhu12345ORCID,Wang Guofu101141213,Su Dangsheng12345,Zhang Tao12345

Affiliation:

1. State Key Laboratory of Catalysis

2. iChEM

3. Dalian Institute of Chemical Physics

4. Chinese Academy of Sciences

5. Dalian 116023

6. Department of Physics

7. Arizona State University

8. Tempe

9. USA

10. State Key Laboratory of Coal Conversion

11. Institute of Coal Chemistry

12. Taiyuan 030001

13. China

Abstract

Alkali metals transform non-selective high-loading Pt/FeOx to a highly chemoselective catalyst by helping to form isolated and electropositive Pt centers.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference45 articles.

1. Selective Catalytic Hydrogenation of Functionalized Nitroarenes: An Update

2. Catalytic syntheses of aromatic amines

3. The Chemistry of Anilines, ed. Z. Rappoport, John Wiley & Sons, New York, 2007

4. U. Siegrist , P.Baumeister, H. U.Blaser and M.Studer, Catalysis of Organic Reactions, Dekker, New York, 1998, vol. 75

5. Transforming Nonselective into Chemoselective Metal Catalysts for the Hydrogenation of Substituted Nitroaromatics

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