Origin of the Ir–Si bond shortening in Ir–NSiN complexes-Reference-Cited by-同舟云学术

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Origin of the Ir–Si bond shortening in Ir–NSiN complexes

Published:2021 Issue:17 Volume:50 Page:5951-5959
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

García-Orduña Pilar¹²³⁴,Fernández Israel⁵⁶⁷⁸⁴^ORCID,Oro Luis A.¹²³⁴^ORCID,Fernández-Alvarez Francisco J.¹²³⁴^ORCID

Affiliation:

1. Departamento de Química Inorgánica-Instituto de Síntesis Química y Catálisis Homogénea (ISQCH)

2. Universidad de Zaragoza–CSIC

3. 50009 Zaragoza

4. Spain

5. Departamento de Química Orgánica I and Centro de Innovación en Química Avanzada

6. Facultad de Ciencias Químicas

7. Universidad Complutense de Madrid

8. 28040-Madrid

Abstract

Ionic contributions are key for the Ir–Si bond shortening !!.

Funder

Gobierno de Aragón

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00473E

Reference92 articles.

1. Monoanionic NSiN-type ligands in transition metal coordination chemistry and catalysis

2. Multidentate silyl ligands in transition metal chemistry

3. Synthesis and structure of a silyl–rhodium(I) complex: stabilization attributable to multisite ‘anchoring’ of a silyl fragment

4. Synthesis and Reactivity of Platinum Group Metal Complexes Featuring the New Pincer-like Bis(phosphino)silyl Ligand [κ3-(2-Ph2PC6H4)2SiMe]− ([PSiP]): Application in the Ruthenium-Mediated Transfer Hydrogenation of Ketones

5. Room temperature benzene C–H activation by a new [PSiP]Ir pincer complex

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Recent Advances on the Chemistry of Transition Metal Complexes with Monoanionic Bidentate Silyl Ligands;ChemPlusChem;2024-07-11

2. Rhodium Complexes with a Pyridine-2-yloxy-silyl-Based N,Si-Ligand: Bonding Situation and Activity as Alkene Hydrogenation Catalysts;Organometallics;2024-01-23

3. Iridium-(κ²-NSi) catalyzed dehydrogenation of formic acid: effect of auxiliary ligands on the catalytic performance;Dalton Transactions;2023

4. Mechanism Insights into the Iridium(III)- and B(C₆F₅)₃-Catalyzed Reduction of CO₂ to the Formaldehyde Level with Tertiary Silanes;Inorganic Chemistry;2022-12-06

5. Synthesis and Characterization of Ir-(κ²-NSi) Species Active toward the Solventless Hydrolysis of HSiMe(OSiMe₃)₂;Inorganic Chemistry;2022-10-04

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