Demethylenative cyclization of 1,7-enynes using α-amino radicals as a traceless initiator enabled by Cu(<scp>i</scp>)-photosensitizers-Reference-Cited by-同舟云学术

Demethylenative cyclization of 1,7-enynes using α-amino radicals as a traceless initiator enabled by Cu(i)-photosensitizers

Published:2024 Issue:50 Volume:60 Page:6399-6402
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Jiang Qinfang¹,Bao Hanyang¹,Peng Yun¹,Zhou Yan¹,Chen Lang¹,Liu Yunkui¹²^ORCID

Affiliation:

1. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou, 310014, P. R. China

2. Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121, China

Abstract

A Cu(i)-photosensitizer-enabled demethylenative radical cyclization of 1,7-enynes to access quinoline-2-(1H)-ones was successfully achieved using α-amino radicals as a traceless radical initiator.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Zhejiang Province

Hangzhou Normal University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01592D

Reference68 articles.

1. J. M.Williams , Preparation of Alkenes: A Practical Approach , Oxford University Press , 1996

2. S.Patai and J.Zabicky , The Chemistry of Alkenes , Interscience Publishers , 1965

3. Enyne Metathesis (Enyne Bond Reorganization)

4. Ethenolysis: A Green Catalytic Tool to Cleave Carbon-Carbon Double Bonds

5. Ring-Closing Metathesis and Related Processes in Organic Synthesis

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