Enhanced solid-state phosphorescence of organoplatinum π-systems by ion-pairing assembly

Author:

Haketa Yohei1ORCID,Komatsu Kaifu1,Sei Hiroi2,Imoba Hiroki2,Ota Wataru3,Sato Tohru45,Murakami Yu1,Tanaka Hiroki1,Yasuda Nobuhiro6,Tohnai Norimitsu2,Maeda Hiromitsu1ORCID

Affiliation:

1. Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, Kusatsu 525-8577, Japan

2. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita 565-0871, Japan

3. MOLFEX, Inc., Kyoto 606-8103, Japan

4. Fukui Institute for Fundamental Chemistry, Kyoto University, Kyoto 606-8103, Japan

5. Department of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan

6. Beamline Division, Japan Synchrotron Radiation Research Institute, Sayo 679-5198, Japan

Abstract

The solid-state ion-pairing assemblies in the form of anion complexes with tetraalkylammonium cations exhibited enhanced phosphorescence owing to the dispersion of emissive hydrogen-bonding 1D-chain PtII complexes by aliphatic cations.

Funder

Japan Society for the Promotion of Science

Ritsumeikan Global Innovation Research Organization, Ritsumeikan University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference62 articles.

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2. Supramolecular Materials for Opto-Electronics , ed. N. Koch , RSC , 2015

3. Discotic Liquid Crystals

4. Crystal Engineering of Organic Optoelectronic Materials

5. Mixed Ionic and Electronic Conduction in Small-Molecule Semiconductors

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