Supported Rh<sub>2</sub>O<sub>3</sub> sub-nanometer size particles for the direct amination of ethylene with piperidine-Reference-Cited by-同舟云学术

Supported Rh₂O₃ sub-nanometer size particles for the direct amination of ethylene with piperidine

Published:2022 Issue:10 Volume:12 Page:3303-3310
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Sengupta Manideepa¹²,Khan Tuhin Suvra¹,Das Subhasis³,Singh Gurmeet¹,Kumar Ravi⁴,Bhattacharya Dibyendu⁴^ORCID,Haider M. Ali⁵^ORCID,Islam Sk Manirul²^ORCID,Bordoloi Ankur¹^ORCID

Affiliation:

1. Nano Catalysis, Light Stock Processing Division, CSIR-Indian Institute of Petroleum, Dehradun-248005, Uttarakhand, India

2. Department of Chemistry, University of Kalyani, Kalyani-741235, West Bengal, India

3. Ruhr-University Bochum, Chemistry and Biochemistry, Universitätsstr. 150, 44801 Bochum, Germany

4. Atomic & Molecular Physics Division, Bhabha Atomic Research Centre, Mumbai 400085, India

5. Department of Chemical Engineering, IIT Delhi, India

Abstract

The π-binding mode of Rh80O120 rather than a stronger σ-binding mode of Rh2O3 (100) surface to CC, reflects the superior catalytic activity of Rh2O3 sub-nanoparticles confined in SiO2 towards ethylenic hydroamination, in contrast to large particle.

Funder

Council of Scientific and Industrial Research, India

University Grants Commission

Board of Research in Nuclear Sciences

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY02209A

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