Aminative annulation of cyano-enynyl esters leading to functionalized cyclopentenones-Reference-Cited by-同舟云学术

Aminative annulation of cyano-enynyl esters leading to functionalized cyclopentenones

Published:2023 Issue:55 Volume:59 Page:8600-8603
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Reddy Chada Raji¹^ORCID,Ganesh Veeramalla¹,Punna Nagender²^ORCID

Affiliation:

1. Department of Organic Synthesis & Process Chemistry, CSIR-Indian Institute of Chemical Technology, Hyderabad-500007, India

2. Department of Fluoro- & Agro-Chemicals, CSIR-Indian Institute of Chemical Technology, Hyderabad-500007, India

Abstract

A novel aminative cyclization of cyanomethylated enynyl-esters with a range of secondary amines to uniquely functionalized cyclopentenones involving difunctionalisation of the alkyne with simultaneous annulation is disclosed.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02213G

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1. Recent advances in the tandem annulation of 1,3-enynes to functionalized pyridine and pyrrole derivatives

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3. Cobalt-Catalyzed Enantioselective Hydroarylation of 1,6-Enynes

4. Pd(0)-Catalyzed Asymmetric 7-Endo Hydroacyloxylative Cyclization of 1,6-Enyne Enabled by an Anion Ligand-Directed Strategy

5. Gold-Catalyzed Synthesis of Chiral Cyclopentadienyl Esters via Chirality Transfer