Computational study of C(sp3)–O bond formation at a PdIV centre-Reference-Cited by-同舟云学术

Computational study of C(sp3)–O bond formation at a PdIV centre

Published:2017 Issue:11 Volume:46 Page:3742-3748
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Canty Allan J.¹²³⁴^ORCID,Ariafard Alireza¹²³⁴^ORCID,Camasso Nicole M.⁵⁶⁷⁸,Higgs Andrew T.⁵⁶⁷⁸,Yates Brian F.¹²³⁴,Sanford Melanie S.⁵⁶⁷⁸

Affiliation:

1. School of Physical Sciences

2. University of Tasmania

3. Hobart

4. Australia

5. Department of Chemistry

6. University of Michigan

7. Ann Arbor

8. USA

Abstract

This report describes a computational study of C(sp³)–OR bond formation from Pd^IV complexes of general structure Pd^IV(CH₂CMe₂-o-C₆H₄-C,C′)(F)(OR)(bpy-N,N′) (bpy = 2,2′-bipyridine).

Funder

National Science Foundation

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00096K

Reference47 articles.

1. Palladium-Catalyzed Oxygenation of Unactivated sp3 C−H Bonds

2. Catalytic aerobic oxidation of substituted 8-methylquinolines in PdII-2,6-pyridinedicarboxylic acid systems

3. Efficient Alkyl Ether Synthesis via Palladium-Catalyzed, Picolinamide-Directed Alkoxylation of Unactivated C(sp3)–H and C(sp2)–H Bonds at Remote Positions

4. Palladium-Catalyzed β-Acyloxylation of Simple Amide via sp3 C–H Activation

5. Diverse sp3 C−H functionalization through alcohol β-sulfonyloxylation

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