Hole-mediated photoredox catalysis: tris(p-substituted)biarylaminium radical cations as tunable, precomplexing and potent photooxidants

Author:

Wu Shangze1234ORCID,Žurauskas Jonas1234ORCID,Domański Michał1234ORCID,Hitzfeld Patrick S.1234ORCID,Butera Valeria5678ORCID,Scott Daniel J.1234ORCID,Rehbein Julia1234ORCID,Kumar Ajeet910114ORCID,Thyrhaug Erling910114ORCID,Hauer Jürgen910114ORCID,Barham Joshua P.1234ORCID

Affiliation:

1. Universität Regensburg

2. Fakültat für Chemie und Pharmazie

3. 93040 Regensburg

4. Germany

5. Central European Institute of Technology

6. CEITEC

7. 61200 Brno

8. Czech Republic

9. Technische Universität München

10. Fakültat für Chemie

11. 85748 Garching b. München

Abstract

Triarylamines are demonstrated as novel, tunable electroactivated photocatalysts that use dispersion precomplexation to harness the full potential of the visible photon (>4.0 V vs. SCE) in anti-Kasha photo(electro)chemical super-oxidations of arenes.

Funder

Alexander von Humboldt-Stiftung

Ministerstvo Školství, Mládeže a Tělovýchovy

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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