Synthesis, structures, and catalytic efficiency in ring opening polymerization of rac-lactide with tridentate vs. bidentate cobalt(ii), zinc(ii), and cadmium(ii) complexes containing N-substituted N,N-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amine ligands-Reference-Cited by-同舟云学术

Synthesis, structures, and catalytic efficiency in ring opening polymerization of rac-lactide with tridentate vs. bidentate cobalt(ii), zinc(ii), and cadmium(ii) complexes containing N-substituted N,N-bis((3,5-dimethyl-1H-pyrazol-1-yl)methyl)amine ligands

Published:2021 Issue:31 Volume:11 Page:18840-18851
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Choe Solhye¹²³⁴^ORCID,Lee Hyosun¹²³⁴^ORCID,Nayab Saira⁵⁶⁷

Affiliation:

1. Department of Chemistry and Green-Nano Materials Research Center

2. Kyungpook National University

3. Daegu

4. Republic of Korea

5. Department of Chemistry

6. Shaheed Benazir Bhutto University

7. Islamic Republic of Pakistan

Abstract

Co(ii), Zn(ii), and Cd(ii) complexes supported by bis-pyrazolyl ligands were applied to the ring-opening polymerization of rac-lactide to produce heterotactic polylactides (PLAs) with superior heterotactic bias i.e. P_r up to 0.94 at −25 °C.

Funder

National Research Foundation

Korea Evaluation Institute of Industrial Technology

Higher Education Commision, Pakistan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA02365A

Reference89 articles.

1. Polylactic Acid Technology