A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)

Author:

Suzuki Ayumi12345,Arai Takahiro67895,Ikenaga Kota67895,Mutoh Yuichiro12345ORCID,Tsuchida Noriko101112135,Saito Shinichi12345,Ishii Youichi67895

Affiliation:

1. Department of Chemistry

2. Faculty of Science

3. Tokyo University of Science

4. Tokyo 162-8601

5. Japan

6. Department of Applied Chemistry

7. Faculty of Science and Engineering

8. Chuo University

9. Tokyo 112-8551

10. Department of Liberal Arts

11. Faculty of Medicine

12. Saitama Medical University

13. Saitama 350-0495

Abstract

The first tellurocarbonyl complex with a half-sandwich structure [CpRuCl(CTe)(H2IMes)] was synthesized and compared with its CE (E = O, S, Se) analogs.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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4. Novel Carbon Monochalcogenide Coordination Mode: [Rh2{μ-SeCMo(CO)2(Tp*)}2(η4-cod)2] (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate; cod = cyclo-octa-1,5-diene)

5. {μ-PbSe}: A Heavy CO Homologue as an Unexpected Ligand

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