Efficient access to a designed phosphapalladacycle catalyst via enantioselective catalytic asymmetric hydrophosphination-Reference-Cited by-同舟云学术

Efficient access to a designed phosphapalladacycle catalyst via enantioselective catalytic asymmetric hydrophosphination

Published:2017 Issue:4 Volume:46 Page:1311-1316
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Xi-Rui¹²³⁴⁵,Yang Xiang-Yuan¹²³⁴⁵^ORCID,Li Yongxin¹²³⁴⁵,Pullarkat Sumod A.¹²³⁴⁵^ORCID,Leung Pak-Hing¹²³⁴⁵^ORCID

Affiliation:

1. Division of Chemistry & Biological Chemistry

2. School of Physical and Mathematical Sciences

3. Nanyang Technological University

4. Singapore 637371

5. Singapore

Abstract

A facile and efficient method for preparing a chiral phosphapalladacycle catalyst via asymmetric catalytic hydrophosphination followed by cyclopalladation was developed. The catalytic potential of the new complex was demonstrated.

Funder

Ministry of Education - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04447F

Reference53 articles.

1. New Chiral Phosphorus Ligands for Enantioselective Hydrogenation

2. Transition Metal-Catalyzed Enantioselective Hydrogenation of Enamines and Imines

3. Asymmetric Carbon−Carbon Bond Formation γ to a Carbonyl Group: Phosphine-Catalyzed Addition of Nitromethane to Allenes

4. Enantioselective Phosphine Organocatalysis

5. Nucleophilic Phosphine Organocatalysis

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