Geometric and electronic structure of a peroxomanganese(iii) complex supported by a scorpionate ligand-Reference-Cited by-同舟云学术

Geometric and electronic structure of a peroxomanganese(iii) complex supported by a scorpionate ligand

Published:2014 Issue:48 Volume:43 Page:17949-17963
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Colmer Hannah E.¹²³,Geiger Robert A.¹²³,Leto Domenick F.¹²³,Wijeratne Gayan B.¹²³,Day Victor W.¹²³,Jackson Timothy A.¹²³

Affiliation:

1. Department of Chemistry

2. University of Kansas

3. Lawrence, USA

Abstract

A peroxomanganese(iii) species with a scorpionate (Tp) ligand is characterized by X-ray crystallography, electron paramagnetic resonance, and magnetic circular dichroism spectroscopy, revealing a distinct electronic structure.

Funder

Division of Chemistry

National Institute of General Medical Sciences

National Institute of Biomedical Imaging and Bioengineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02483D

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1. SECOND-SPHERE TUNING OF THE METAL ION REDUCTION POTENTIALS IN IRON AND MANGANESE SUPEROXIDE DISMUTASES

2. Superoxide dismutases: active sites that save, but a protein that kills

3. Probing the Geometric and Electronic Structures of the Low-Temperature Azide Adduct and the Product-Inhibited Form of Oxidized Manganese Superoxide Dismutase

4. Kinetic studies of superoxide dismutases: properties of the manganese-containing protein from Thermus thermophilus

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