Unactivated C(sp3)–H hydroxylation through palladium catalysis with H2O as the oxygen source-Reference-Cited by-同舟云学术

Unactivated C(sp3)–H hydroxylation through palladium catalysis with H2O as the oxygen source

Published:2015 Issue:80 Volume:51 Page:14929-14932
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Hu Jiantao¹²³⁴⁵,Lan Tianlong¹²³⁴⁵,Sun Yihua⁶⁷⁸⁹⁵,Chen Hui⁶⁷⁸⁹⁵,Yao Jiannian⁶⁷⁸⁹⁵,Rao Yu¹²³⁴⁵

Affiliation:

1. MOE Key Laboratory of Protein Sciences

2. Department of Pharmacology and Pharmaceutical Sciences

3. School of Medicine

4. Tsinghua University

5. Beijing

6. Beijing National Laboratory for Molecular Sciences (BNLMS)

7. CAS Key Laboratory of Photochemistry

8. Institute of Chemistry

9. Chinese Academy of Sciences

Abstract

A novel palladium catalyzed hydroxylation of unactivated aliphatic C(sp³)–H bonds was successfully developed. Different from conventional methods, water serves as the hydroxyl group source in the reaction. This reaction demonstrates broad functional group tolerance.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC04952K

Reference54 articles.

1. Arene C–H functionalisation using a removable/modifiable or a traceless directing group strategy

2. Towards mild metal-catalyzed C–H bond activation

3. Ruthenium(II)-Catalyzed C–H Bond Activation and Functionalization

4. Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

5. Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

Cited by 39 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Palladium-Catalyzed C(sp³)–H Nitrooxylation of Aliphatic Carboxamides with Practical Oxidants;The Journal of Organic Chemistry;2024-01-18

2. Integrated synthesis of 3,4-carbazoquinone alkaloids N-Me-carbazoquinocin A, B and D–F;RSC Advances;2024

3. Organohypervalent heterocycles;Chemical Society Reviews;2024

4. Ligand-Enabled γ-C(sp³)–H Hydroxylation of Free Amines with Aqueous Hydrogen Peroxide;Journal of the American Chemical Society;2023-11-20

5. Nature's Blueprint: Chelation‐Assisted C−H Functionalization for Selective and Efficient Reactions in Aqueous Media;Israel Journal of Chemistry;2023-05-31