BF3·Et2O as a metal-free catalyst for direct reductive amination of aldehydes with amines using formic acid as a reductant-Reference-Cited by-同舟云学术

BF3·Et2O as a metal-free catalyst for direct reductive amination of aldehydes with amines using formic acid as a reductant

Published:2021 Issue:14 Volume:23 Page:5205-5211
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Luo Zhenli¹²³⁴,Pan Yixiao¹²³⁴⁵,Yao Zhen¹²³⁴,Yang Ji¹²³⁴,Zhang Xin¹²³⁴,Liu Xintong¹²³⁴,Xu Lijin¹²³⁴^ORCID,Fan Qing-Hua⁵⁶⁷⁸^ORCID

Affiliation:

1. Department of Chemistry

2. Renmin University of China

3. Beijing 100872

4. China

5. Institute of Chemistry

6. Chinese Academy of Sciences and University of Chinese Academy of Sciences

7. Beijing 100190

8. P. R. China

Abstract

A versatile metal- and base-free direct reductive amination of aldehydes with primary and secondary amines catalyzed by inexpensive BF₃·Et₂O using formic acid as a reductant has been developed.

Funder

National Natural Science Foundation of China

Renmin University of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC01468D

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4. F. Shi and X.Cui , Catalytic amination for N-alkyl amine synthesis , Academic Press , 2018

5. Biobased Amines: From Synthesis to Polymers; Present and Future

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