Hybrid compound based on diethylenetriaminecopper(ii) cations and scarce V-monosubstituted β-octamolybdate as water oxidation catalyst-Reference-Cited by-同舟云学术

Hybrid compound based on diethylenetriaminecopper(ii) cations and scarce V-monosubstituted β-octamolybdate as water oxidation catalyst

Published:2021 Issue:51 Volume:11 Page:32119-32125
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Buvailo Halyna I.¹^ORCID,Makhankova Valeriya G.²^ORCID,Kokozay Vladimir N.¹,Omelchenko Iryna V.³^ORCID,Shishkina Svitlana V.³^ORCID,Bieńko Alina⁴^ORCID,Pavliuk Mariia V.⁵,Shylin Sergii I.⁵^ORCID

Affiliation:

1. Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska Street 64/13, 01601 Kyiv, Ukraine

2. Institute of High Technologies, Taras Shevchenko National University of Kyiv, Hlushkova Avenue, 4g, 03022, Kyiv, Ukraine

3. Institute for Single Crystals, National Academy of Sciences of Ukraine, Nauky Ave 60, 61001 Kharkiv, Ukraine

4. Faculty of Chemistry, University of Wroclaw, F. Joliot-Curie 14, 50-383 Wroclaw, Poland

5. Department of Chemistry – Ångström Laboratory, Uppsala University, P. O. Box 523, 75120 Uppsala, Sweden

Abstract

A new hybrid compound (NH4){[Cu(dien)(H2O)2]2[β-VMo7O26]}·1.5H2O was employed in homogeneous water oxidation catalysis. At pH 8.0, its efficiency attains 0.19 turnovers per second, supported by the relatively mild water oxidation overpotential of 0.54 V.

Funder

Vardalinstitutet

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA05030C

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