Dual wavelength asymmetric photochemical synthesis with circularly polarized light-Reference-Cited by-同舟云学术

Dual wavelength asymmetric photochemical synthesis with circularly polarized light

Published:2015 Issue:7 Volume:6 Page:3853-3862
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Richardson Robert D.¹²³⁴⁵,Baud Matthias G. J.¹²³⁴⁵,Weston Claire E.¹²³⁴⁵,Rzepa Henry S.¹²³⁴⁵,Kuimova Marina K.¹²³⁴⁵,Fuchter Matthew J.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Imperial College London

3. South Kensington Campus

4. London

5. UK

Abstract

An asymmetric photchemical synthesis of a dihyrohelicene demonstrates two wavelengths of circularly polarized (CP) light can be used to ensure the enantiomeric induction intrinsic to each step can combine additively; significantly increasing the asymmetric induction possible over a single wavelength approach.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C4SC03897E

Reference38 articles.

1. Absolute Asymmetric Synthesis: The Origin, Control, and Amplification of Chirality

2. Asymmetric photochemical reactions in solution

3. Asymmetric Photochemistry and Photochirogenesis

4. True and false chirality and absolute asymmetric synthesis

5. Supernovae and life

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