2,2,2-Trifluoroethanol as a solvent to control nucleophilic peptide arylation
Author:
Affiliation:
1. Durham University
2. Department of Chemistry
3. Durham
4. UK
5. School of Pharmacy and Biomolecular Sciences
6. Byrom Street Campus
7. Liverpool John Moores University
8. Liverpool
Abstract
Trifluoroethanol enables selective perfluoro-heteroaromatic peptide arylation of cysteine residues.
Funder
Seventh Framework Programme
Engineering and Physical Sciences Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB00295E
Reference31 articles.
1. G. Sandford , e-EROS Encyclopedia of Reagents for Organic Synthesis, 2005
2. 93. Heterocyclic polyfluoro-compounds. Part IV. Nucleophilic substitution in pentafluoropyridine: the preparation and properties of some 4-substituted 2,3,5,6-tetrafluoropyridines
3. The preparation and properties of polyfluoro aromatic and heteroaromatic compounds
4. Macrocycles from polyfluoro-pyridine derivatives
5. Tetrahydropyrido[3,4-b]pyrazine Scaffolds from Pentafluoropyridine
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