An easy access to carboxylic acids via Pd-catalyzed hydrocarboxylation of olefins with HCOOLi as a CO surrogate under mild conditions

Author:

Wang Yang12345,Zeng Yongming12345,Yang Bangyu12345,Shi Yian12345

Affiliation:

1. State Key Laboratory of Coordination Chemistry

2. Collaborative Innovation Center of Chemistry for Life Sciences

3. Center for Multimolecular Organic Chemistry

4. School of Chemistry and Chemical Engineering

5. Nanjing University

Abstract

This paper describes an easy access to carboxylic acids via Pd-catalyzed hydrocarboxylation of olefins with HCOOLi and Ac2O under mild conditions without using external CO gas.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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5. B. E. Ali and H.Alper, in Handbook of Organopalladium Chemistry for Organic Synthesis, ed. E. Negishi, John Wiley & Sons, Inc., New York, 2002, p. 2333

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