Metallic salt-catalyzed direct indium insertion into alkyl iodides and their applications in cross-coupling reactions-Reference-Cited by-同舟云学术

Metallic salt-catalyzed direct indium insertion into alkyl iodides and their applications in cross-coupling reactions

Published:2019 Issue:3 Volume:6 Page:313-318
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Bing-Zhi¹²³⁴⁵,Wang Chuang-Xin¹²³⁴⁵,Jing Zhen-Hua¹²³⁴⁵,Chu Xue-Qiang¹²³⁴⁵,Loh Teck-Peng¹²³⁴⁵^ORCID,Shen Zhi-Liang¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Advanced Synthesis

2. School of Chemistry and Molecular Engineering

3. Jiangsu National Synergetic Innovation Center for Advanced Materials

4. Nanjing Tech University

5. Nanjing 211816

Abstract

An efficient method for the synthesis of alkyl indium reagents via an indium(iii) or lead(ii) halide-catalyzed direct insertion of indium into alkyl iodides is developed. NMR and ESI-MS analyses indicated the formation of a mixture of an alkyl indium dihalide (RInX₂) and a dialkyl indium halide (R₂InX).

Funder

Nanjing Tech University

Nanyang Technological University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C8QO01244J

Reference55 articles.

1. Organoindium Reagents: The Preparation and Application in Organic Synthesis

2. Transition metal-catalyzed cross-coupling reactions using organoindium reagents