Methylation of olefins with ketene in zeotypes and its implications for the direct conversion of syngas to light olefins: a periodic DFT study
Author:
Affiliation:
1. State Key Laboratory of Green Chemical Engineering and Industrial Catalysis
2. SINOPEC Shanghai Research Institute of Petrochemical Technology
3. Shanghai 201208
4. China
Abstract
Theoretical calculations suggested that the associative pathway other than the dissociative pathway dominates the methylation of tetramethylethene with ketene in H-SAPO-34, and the former pathway is more sensitive to acid strength than the latter one in CHA-structured zeotypes.
Publisher
Royal Society of Chemistry (RSC)
Subject
Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY01095D
Reference48 articles.
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