Tryptophan/copper-catalyzed aromatization reaction of chiral cyclohexanones to phenols
Author:
Affiliation:
1. Catalytic Hydrogenation Research Centre
2. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology
3. Zhejiang University of Technology
4. Hangzhou
5. China
Abstract
By merging organocatalysis with copper catalysis, a simple and efficient methodology for the synthesis of chiral phenols through tryptophan/CuBr2 catalyzed bromination/debromination aromatization of chiral cyclohexanone derivatives was developed.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/OB/C7OB01114H
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