A general photocatalytic hydrodefluorination and defluoroalkylation of electronically-variable ArCF<sub>3</sub> by changing commercially-available arenethiolates-Reference-Cited by-同舟云学术

A general photocatalytic hydrodefluorination and defluoroalkylation of electronically-variable ArCF₃ by changing commercially-available arenethiolates

Published:2024 Issue:8 Volume:26 Page:4518-4527
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Jiang Yuanyang¹,Han Chenxiu¹,Guo Zipeng¹,Dai Zhenyang¹,Liang Guangchao²^ORCID,Guo Shuo¹^ORCID,Szymczak Nathaniel K.³^ORCID,Tang Pingping⁴

Affiliation:

1. College of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, P.R. China

2. Academy of Advanced Interdisciplinary Research, Xidian University, Xi'an, Shaanxi 710071, P.R. China

3. Department of Chemistry, University of Michigan, 930 N. University, Ann Arbor, Michigan 48109, USA

4. State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

Abstract

The selection of electronically-different thiolate-based photosensitizers is employed to achieve a precise and specific C–F bond defluorination of a broad range of trifluoromethylarenes, enabling the synthesis of 88 α,α-difluoromethyl compounds.

Funder

National Natural Science Foundation of China

Inner Mongolia Autonomous Region

Inner Mongolia University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D3GC05041F

Reference62 articles.

1. Late-stage difluoromethylation: concepts, developments and perspective

2. The Fluorination of C−H Bonds: Developments and Perspectives

3. Frontiers in Radical Fluoromethylation by Visible‐Light Organic Photocatalysis

4. Progress in Visible Light‐Induced Difluroalkylation of Olefins

5. Recent progress on selective deconstructive modes of halodifluoromethyl and trifluoromethyl-containing reagents

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