Coupling thulium 4f orbitals with Ni3Fe LDH loaded with Pt to form an electronic buffer band for catalyzing alkaline overall water splitting

Author:

Yang Xinping1,Li Shucheng1,Zhang Yan1,Qiu Fagui1,Sun Yanbin1,Ning Weikun1,Tao Qinglong2,Li Wenqing3,Miao Shiding1ORCID

Affiliation:

1. Key Laboratory of Automobile Materials of Ministry of Education, School of Materials Science and Engineering, Solid Waste Recycling Engineering Research Centre of Jilin Province, Jilin University, Changchun, 130022, China

2. Zhejiang Taihua New Material Co., Ltd, Jiaxing, Zhejiang Prov., 314011, China

3. Key Laboratory of Mineral Resources Evaluation in Northeast Asia, Ministry of Natural Resources, Changchun 130061, China

Abstract

When thulium is doped into Ni3Fe LDH, coupling thulium 4f orbitals with the Ni3Fe LDH system forms an electronic buffer band and Pt loading catalyzes alkaline overall water splitting.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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