Reaction of porphyrin-based surface-anchored metal–organic frameworks caused by prolonged illumination

Author:

Adams Michael1234ORCID,Baroni Nicolò1234,Oldenburg Michael1234,Kraffert Felix56784ORCID,Behrends Jan56784ORCID,MacQueen Rowan W.91084ORCID,Haldar Ritesh1124ORCID,Busko Dmitry1234,Turshatov Andrey1234ORCID,Emandi Ganapathi1213141516,Senge Mathias O.1213141516ORCID,Wöll Christof1124ORCID,Lips Klaus56784ORCID,Richards Bryce S.123417ORCID,Howard Ian A.123417ORCID

Affiliation:

1. Institute of Microstructure Technology

2. Karlsruhe Institute of Technology

3. Eggenstein-Leopoldshafen

4. Germany

5. Fachbereich Physik

6. Freie Universität Berlin

7. Berlin Joint EPR Lab

8. Berlin

9. Institute for Nanospectroscopy

10. Helmholtz-Zentrum Berlin für Materialien und Energie GmbH

11. Institute of Functional Interfaces

12. School of Chemistry

13. Trinity Biomedical Sciences Institute

14. Trinity College Dublin

15. The University of Dublin

16. Dublin

17. Light Technology Institute

Abstract

Upon prolonged illumination photoproducts are created in porphyrin-based metal–organic frameworks that limit the triplet exciton lifetime by charge-transfer quenching.

Funder

Helmholtz-Gemeinschaft

Deutsche Forschungsgemeinschaft

Science Foundation Ireland

Baden-Württemberg Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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