An iron(<scp>ii</scp>)-based metalloradical system for intramolecular amination of C(sp<sup>2</sup>)–H and C(sp<sup>3</sup>)–H bonds: synthetic applications and mechanistic studies-Reference-Cited by-同舟云学术

An iron(ii)-based metalloradical system for intramolecular amination of C(sp²)–H and C(sp³)–H bonds: synthetic applications and mechanistic studies

Published:2022 Issue:40 Volume:13 Page:11817-11828
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Das Sandip Kumar¹²,Das Subrata¹,Ghosh Supratim³,Roy Satyajit¹,Pareek Monika³,Roy Brindaban²,Sunoj Raghavan B.³^ORCID,Chattopadhyay Buddhadeb¹^ORCID

Affiliation:

1. Division of Molecular Synthesis & Drug Discovery, Centre of Biomedical Research, SGPGIMS Campus, Raebareli Road, Lucknow 226014, Uttar Pradesh, India

2. Department of Chemistry, University of Kalyani, Nadia, Kalyani 741235, West Bengal, India

3. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400076, India

Abstract

A catalytic system for intramolecular C(sp2)–H and C(sp3)–H amination of substituted tetrazolopyridines has been successfully developed.

Funder

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC03505G

Reference57 articles.

1. Catalytic and Biocatalytic Iron Porphyrin Carbene Formation: Effects of Binding Mode, Carbene Substituent, Porphyrin Substituent, and Protein Axial Ligand

2. Biosynthesis and Metabolism of Cyclopropane Rings in Natural Compounds

3. Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?

4. Asymmetric Induction and Enantiodivergence in Catalytic Radical C–H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution

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