Y-shaped tricatenar azobenzenes – functional liquid crystals with synclinic–anticlinic transitions and spontaneous helix formation

Author:

Alaasar Mohamed12345ORCID,Poppe Silvio1234,Cao Yu678910,Chen Changlong678910,Liu Feng678910ORCID,Zhu Chenhui11121314ORCID,Tschierske Carsten1234ORCID

Affiliation:

1. Institute of Chemistry

2. Martin Luther University Halle-Wittenberg

3. D-06120 Halle (Saale)

4. Germany

5. Department of Chemistry

6. State Key Laboratory for Mechanical Behaviour of Materials

7. Shaanxi International Research Center for Soft Matter

8. School of Materials Science & Engineering

9. Xi’an Jiaotong University

10. Xi’an 710049

11. Advanced Light Source

12. Lawrence Berkeley National Laboratory

13. Berkeley

14. USA

Abstract

The photoisomerizable functional azobenzene unit is organized in synclinic hexatic, anticlinic smectic and bicontinuous cubic liquid crystalline phases as well as in achiral or mirror symmetry broken isotropic network liquids.

Funder

National Natural Science Foundation of China

Deutsche Forschungsgemeinschaft

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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