Unique solubility of polyoxoniobate salts in methanol: coordination to cations and POM methylation
Author:
Affiliation:
1. Nikolaev Institute of Inorganic Chemistry SB RAS
2. Novosibirsk
3. Russia
4. Novosibirsk State University
5. Serveis Centrals d’Instrumentació Científica
6. Universitat Jaume I
7. 12071 Castelló
8. Spain
Abstract
In methanolic solutions of A4[{LM′}2M6O19] ({LM′} = {Cp*Rh}2+, {Cp*Ir}2+, {(C6H6)Ru}2+; M = Nb, Ta; A = Na, K) formation of methoxo complexes [{LM′}2M6O19−n(OMe)n] (n = 1–3) and coordination of CH3OH to A+ take place.
Funder
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA23918D
Reference39 articles.
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3. Coordination-Induced Condensation of [Ta6O19]8–: Synthesis and Structure of [{(C6H6)Ru}2Ta6O19]4– and [{(C6H6)RuTa6O18}2(μ-O)]10−
4. Platinum polyoxoniobates
5. A new Keggin-like niobium-phosphate cluster that reacts reversibly with hydrogen peroxide
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