Calix[6]arenes with halogen bond donor groups as selective and efficient anion transporters

Author:

Singh Anurag1ORCID,Torres-Huerta Aaron1ORCID,Vanderlinden Tom12,Renier Nathan1ORCID,Martínez-Crespo Luis1ORCID,Tumanov Nikolay3ORCID,Wouters Johan3ORCID,Bartik Kristin1ORCID,Jabin Ivan2ORCID,Valkenier Hennie1ORCID

Affiliation:

1. Université libre de Bruxelles (ULB), Ecole polytechnique de Bruxelles, Engineering Molecular NanoSystems, Avenue Franklin Roosevelt 50, 1050 Brussels, Belgium

2. Université libre de Bruxelles (ULB), Faculty of science, Laboratoire de Chimie Organique, Avenue Franklin Roosevelt 50, 1050 Brussels, Belgium

3. Namur Institute of Structured Matter and Namur Research Institute for Life Sciences, Department of Chemistry, University of Namur, 61 rue de Bruxelles, B-5000 Namur, Belgium

Abstract

A calix[6]arene with three preorganised halogen bond donating groups gives >100-fold selectivity for Cl uniport over HCl symport, in contrast to analogous compounds with strong hydrogen bond donating groups.

Funder

H2020 European Research Council

Fonds De La Recherche Scientifique - FNRS

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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