Dysprosium complexes bearing unsupported DyIII–GeII/SnIImetal–metal bonds as single-ion magnets-Reference-Cited by-同舟云学术

Dysprosium complexes bearing unsupported DyIII–GeII/SnIImetal–metal bonds as single-ion magnets

Published:2019 Issue:57 Volume:55 Page:8250-8253
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Chen Shi-Ming¹²³⁴⁵^ORCID,Xiong Jin¹²³⁴⁵,Zhang Yi-Quan⁶⁷⁸⁹¹⁰^ORCID,Ma Fang¹¹¹²¹³¹⁰,Sun Hao-Ling¹¹¹²¹³¹⁰^ORCID,Wang Bing-Wu¹²³⁴⁵^ORCID,Gao Song¹²³⁴⁵^ORCID

Affiliation:

1. Beijing National Laboratory of Molecular Science

2. State Key Laboratory of Rare Earth Materials Chemistry and Applications

3. College of Chemistry and Molecular Engineering

4. Peking Ufniversity

5. Beijing 100871

6. Jiangsu Key Laboratory for NSLSCS

7. School of Physical Science and Technology

8. Nanjing Normal University

9. Nanjing 210023

10. P. R. China

11. College of Chemistry

12. Beijing Normal University

13. Beijing

Abstract

We report here two dysprosium complexes bearing unsupported Dy–Ge/Sn metal–metal bonds which contain relatively large covalency. Both complexes can exhibit slow relaxation of magnetization at zero field with energy barriers of 485 and 620 K, respectively, and the blocking temperature of 6 K.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC00388F

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