Copper-promoted aerial oxidation of benzothiadiazines: access to benzothiadiazine S-oxide heterocycles
Author:
Affiliation:
1. Department of Chemistry
2. The University of Cambridge
3. Cambridge
4. UK
5. Department of Chemistry and Biochemistry
6. The University of Windsor
7. Windsor ON
8. Canada N9B 3P4
9. Brock University
10. St Catharines
11. Canada L2S 3A1
Abstract
Aerial oxidation of benzothiadiazines selectively affords the corresponding benzothiadiazine S-oxides in the presence of Cu2+ ions. Structural studies reveal that the S-oxide appears to be a strong hydrogen-bond acceptor.
Funder
Natural Sciences and Engineering Research Council of Canada
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03467H
Reference25 articles.
1. Experimental and Theoretical Studies of Fused-Ring Persistent [1,2,4]Thiadiazinyl Radicals
2. Synthesis of Liquid Crystalline 4H-Benzo[1,2,4]thiadiazines and Generation of Persistent Radicals
3. Resonance stabilized bis-thiadiazinyl radicals
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