Simulation of the cyclic voltammetric response of an outer-sphere redox species with inclusion of electrical double layer structure and ohmic potential drop-Reference-Cited by-同舟云学术

Simulation of the cyclic voltammetric response of an outer-sphere redox species with inclusion of electrical double layer structure and ohmic potential drop

Published:2023 Issue:11 Volume:25 Page:7832-7846
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Levey Katherine J.¹²^ORCID,Edwards Martin A.³^ORCID,White Henry S.⁴^ORCID,Macpherson Julie V.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK

2. Centre for Diamond Science and Technology, University of Warwick, Coventry, CV4 7AL, UK

3. Department of Chemistry & Biochemistry, University of Arkansas, Fayetteville, AR 72701, USA

4. Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, UT 84112, USA

Abstract

A finite-element model incorporating electrostatics allows simulation of the influence of the interfacial electric double layer structure, ion migration and ohmic potential drop on the voltammetry of a 1e outer-sphere redox system.

Funder

Engineering and Physical Sciences Research Council

Office of Naval Research

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00098B

Reference54 articles.

1. Theory of the voltammetric response of electrodes of submicron dimensions. Violation of electroneutrality in the presence of excess supporting electrolyte